Studies on Oxidation of Alcohols by Cerium (IV)-dimer in Aqueous Nitric acid
نویسندگان
چکیده
The oxidation of alcohols, n-propanol, 2-methoxy ethanol and 2-ethoxy by cerium (IV) in nitric acid leads to the formation corresponding aldehydes. reaction is first order with respect Ce(IV). A Michaelis-Menten type kinetics observed alcohols. retarded initial [Ce(IV)] increase concentration oxidant. exhibits participation 2 mole 1 It has been concluded that Ce(IV)-dimer participate process free radical through complex ion medium.
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ژورنال
عنوان ژورنال: Oriental journal of chemistry
سال: 2022
ISSN: ['0970-020X', '2231-5039']
DOI: https://doi.org/10.13005/ojc/380116